Aligning Toolbar Buttons
The following XAML shows how to align the toolbar buttons in the center of the group panel:
<c1:C1ToolbarGroup Header="Group" >
<c1:C1ToolbarGroup.ItemsPanel>
<ItemsPanelTemplate>
<c1:C1ToolbarGroupPanel HorizontalAlignment="Center" />
</ItemsPanelTemplate>
</c1:C1ToolbarGroup.ItemsPanel>